Here's the First Season with the cast members for each episode. The order I put them in are neither the Production nor the Broadcast order. Instead, after hours of deciding, I've put the episodes in this order, which I feel they are best viewed in.

Chico and the Man
Season One: 1974-1975

#01. “Pilot”
Ed Brown---------------------- Jack Albertson
Chico Rodriguez-------------- Freddie Prinze

#02. “Second Thoughts”
Ed Brown---------------------- Jack Albertson
Chico Rodriguez-------------- Freddie Prinze

#03. “Borrowed Trouble”
Ed Brown---------------------- Jack Albertson
Chico Rodriguez-------------- Freddie Prinze
Mando-------------------------- Isaac Ruiz

#04. “Old Dog”
Ed Brown---------------------- Jack Albertson
Chico Rodriguez-------------- Freddie Prinze
Mabel--------------------------- Bonnie Boland

#05. “New Suit”
Ed Brown---------------------- Jack Albertson
Chico Rodriguez-------------- Freddie Prinze
Louie Wilson------------------ Scatman Crothers

#06. “The Manuel Who Came to Dinner”
Ed Brown---------------------- Jack Albertson
Chico Rodriguez-------------- Freddie Prinze

#07. “No Room in the Garage”
Ed Brown---------------------- Jack Albertson
Chico Rodriguez-------------- Freddie Prinze

#08. “Natural Causes”
Ed Brown---------------------- Jack Albertson
Chico Rodriguez-------------- Freddie Prinze
Mabel--------------------------- Bonnie Boland

#09. “E. Pluribus Used Car”
Ed Brown---------------------- Jack Albertson
Chico Rodriguez-------------- Freddie Prinze
Louie Wilson------------------ Scatman Crothers
Mando-------------------------- Isaac Ruiz

#10. “Lifestyle”
Ed Brown---------------------- Jack Albertson
Chico Rodriguez-------------- Freddie Prinze
Louie Wilson------------------- Scatman Crothers

#11. “Veterans”
Ed Brown---------------------- Jack Albertson
Chico Rodriguez-------------- Freddie Prinze
Louie Wilson------------------ Scatman Crothers

#12. “The Letter”
Ed Brown---------------------- Jack Albertson
Chico Rodriguez-------------- Freddie Prinze
Louie Wilson------------------ Scatman Crothers
Mando------------------------- Isaac Ruiz
Mabel--------------------------- Bonnie Boland

#13. “The Garage Sale”
Ed Brown---------------------- Jack Albertson
Chico Rodriguez-------------- Freddie Prinze

#14. “Ed Steps Out”
Ed Brown---------------------- Jack Albertson
Chico Rodriguez-------------- Freddie Prinze

#15. “Out of Sight”
Ed Brown---------------------- Jack Albertson
Chico Rodriguez-------------- Freddie Prinze

#16. “The Beard”
Ed Brown---------------------- Jack Albertson
Chico Rodriguez-------------- Freddie Prinze
Louie Wilson------------------ Scatman Crothers

#17. “If I Were a Rich Man”
Ed Brown---------------------- Jack Albertson
Chico Rodriguez-------------- Freddie Prinze
Louie Wilson------------------ Scatman Crothers
Mando-------------------------- Isaac Ruiz

#18. “Sammy Steps In”
Ed Brown---------------------- Jack Albertson
Chico Rodriguez-------------- Freddie Prinze
Louie Wilson------------------ Scatman Crothers
Mabel--------------------------- Bonnie Boland

#19. “The Doctor Story”
Ed Brown---------------------- Jack Albertson
Chico Rodriguez-------------- Freddie Prinze
Mabel--------------------------- Bonnie Boland

#20. “The Giveaway”
Ed Brown---------------------- Jack Albertson
Chico Rodriguez-------------- Freddie Prinze
Louie Wilson------------------ Scatman Crothers

#21. “Long Live the Man”
Ed Brown---------------------- Jack Albertson
Chico Rodriguez-------------- Freddie Prinze
Louie Wilson------------------ Scatman Crothers
Mando-------------------------- Isaac Ruiz
Mabel--------------------------- Bonnie Boland

#22. “Louie’s Retirement”
Ed Brown---------------------- Jack Albertson
Chico Rodriguez-------------- Freddie Prinze
Louie Wilson------------------ Scatman Crothers

Chico and the Man
Season Two: 1975-1976

#23. “This Hallowed Garage”
Ed Brown---------------------- Jack Albertson
Chico Rodriguez-------------- Freddie Prinze
Louie Wilson------------------ Scatman Crothers
Reverend Bemis--------------- Ronny Graham

#24. “Chico and the Van”
Ed Brown---------------------- Jack Albertson
Chico Rodriguez-------------- Freddie Prinze
Louie Wilson------------------ Scatman Crothers

#25. “Play Gypsy”
Ed Brown---------------------- Jack Albertson
Chico Rodriguez-------------- Freddie Prinze
*Miklos, the gypsy------------ Avery Schreiber

#26. “Auntie Connie”
Ed Brown---------------------- Jack Albertson
Chico Rodriguez-------------- Freddie Prinze
Louie Wilson------------------ Scatman Crothers
Reverend Bemis--------------- Ronny Graham

#27. “Paint Job”
Ed Brown---------------------- Jack Albertson
Chico Rodriguez-------------- Freddie Prinze
Louie Wilson------------------- Scatman Crothers
Reverend Bemis--------------- Ronny Graham

#28. “The Juror”
Ed Brown---------------------- Jack Albertson
Chico Rodriguez-------------- Freddie Prinze
Louie Wilson------------------ Scatman Crothers
Reverend Bemis--------------- Ronny Graham

#29. “Misfortune Teller”
Ed Brown---------------------- Jack Albertson
Chico Rodriguez-------------- Freddie Prinze
Reverend Bemis--------------- Ronny Graham
*Miklos, the gypsy------------ Avery Schreiber

#30. “The Strike”
Ed Brown---------------------- Jack Albertson
Chico Rodriguez-------------- Freddie Prinze
Louie Wilson------------------ Scatman Crothers
Mando-------------------------- Isaac Ruiz

#31. “The Disappearance”
Ed Brown---------------------- Jack Albertson
Chico Rodriguez-------------- Freddie Prinze
Louie Wilson------------------- Scatman Crothers
*Flora-------------------------- Carol Cook

#32. “Mister Butterfly”
Ed Brown---------------------- Jack Albertson
Chico Rodriguez-------------- Freddie Prinze

#33. “Ms. Liz”
Ed Brown---------------------- Jack Albertson
Chico Rodriguez-------------- Freddie Prinze
Reverend Bemis--------------- Ronny Graham
*Liz Garcia--------------------- Jeannie Linero

#34. “Bird in a Gilded Cage”
Ed Brown---------------------- Jack Albertson
Chico Rodriguez-------------- Freddie Prinze


#35. “The Big Brush-Off”
Ed Brown---------------------- Jack Albertson
Chico Rodriguez-------------- Freddie Prinze
Louie Wilson------------------ Scatman Crothers

#36. “The Invention”
Ed Brown---------------------- Jack Albertson
Chico Rodriguez--------------- Freddie Prinze
Louie Wilson------------------- Scatman Crothers
Reverend Bemis--------------- Ronny Graham

#37. “The Dream”
Ed Brown---------------------- Jack Albertson
Chico Rodriguez-------------- Freddie Prinze
Louie Wilson------------------ Scatman Crothers

#38. “The Hypnotist”
Ed Brown---------------------- Jack Albertson
Chico Rodriguez-------------- Freddie Prinze
Louie Wilson------------------ Scatman Crothers
Reverend Bemis--------------- Ronny Graham
*Flora-------------------------- Carol Cook

#39. “Reverend Bemis’ Altar Ego”
Ed Brown---------------------- Jack Albertson
Chico Rodriguez-------------- Freddie Prinze
Reverend Bemis--------------- Ronny Graham

#40. “The Accident”
Ed Brown---------------------- Jack Albertson
Chico Rodriguez-------------- Freddie Prinze
Louie Wilson------------------ Scatman Crothers
*Liz Garcia-------------------- Jeannie Linero

#41. “Chico’s Cousin Pepe”
Ed Brown---------------------- Jack Albertson
Chico Rodriguez-------------- Freddie Prinze
*Liz Garcia-------------------- Jeannie Linero

#42. “Return of Aunt Connie”
Ed Brown---------------------- Jack Albertson
Chico Rodriguez-------------- Freddie Prinze

#43. “Too Many Crooks”
Ed Brown---------------------- Jack Albertson
Chico Rodriguez-------------- Freddie Prinze

#44. “The Face Job”
Ed Brown---------------------- Jack Albertson
Chico Rodriguez-------------- Freddie Prinze
Louie Wilson------------------ Scatman Crothers
*Liz Garcia-------------------- Jeannie Linero
*Flora-------------------------- Carol Cook

Chico and the Man
Season Three: 1976-1977

#45. “Della Moves In”
Ed Brown---------------------- Jack Albertson
Chico Rodriguez-------------- Freddie Prinze
Louie Wilson------------------ Scatman Crothers
Della Rogers------------------- Della Reese
Salvador------------------------ Danny Mora

#46. “The Second Coming of Della”
Ed Brown---------------------- Jack Albertson
Chico Rodriguez-------------- Freddie Prinze
Louie Wilson------------------ Scatman Crothers
Della Rogers------------------- Della Reese

#47. “Chico Packs His Bags”
Ed Brown---------------------- Jack Albertson
Chico Rodriguez-------------- Freddie Prinze
Louie Wilson------------------ Scatman Crothers

#48. “Chico’s Problem”
Ed Brown---------------------- Jack Albertson
Chico Rodriguez-------------- Freddie Prinze
Louie Wilson------------------ Scatman Crothers
Della Rogers------------------- Della Reese

#49. “Ed Brown Vs. the IRS”
Ed Brown---------------------- Jack Albertson
Chico Rodriguez-------------- Freddie Prinze
Louie Wilson------------------ Scatman Crothers

#50. “In Your Hat”
Ed Brown---------------------- Jack Albertson
Chico Rodriguez-------------- Freddie Prinze

#51. “Ed’s Recuperation”
Ed Brown---------------------- Jack Albertson
Chico Rodriguez-------------- Freddie Prinze
Louie Wilson------------------ Scatman Crothers
Della Rogers------------------- Della Reese

#52. “Old is Gold”
Ed Brown---------------------- Jack Albertson
Chico Rodriguez-------------- Freddie Prinze
Della Rogers------------------- Della Reese

#53. “Mucho Macho Ed”
Ed Brown---------------------- Jack Albertson
Chico Rodriguez-------------- Freddie Prinze
Louie Wilson------------------ Scatman Crothers

#54. “The Dress”
Ed Brown---------------------- Jack Albertson
Chico Rodriguez-------------- Freddie Prinze
Louie Wilson------------------ Scatman Crothers
Salvador------------------------ Danny Mora

#55. “Minority of One”
Ed Brown---------------------- Jack Albertson
Chico Rodriguez-------------- Freddie Prinze
Della Rogers------------------- Della Reese

#56. “Morgan and the Man”
Ed Brown---------------------- Jack Albertson
Chico Rodriguez-------------- Freddie Prinze
Louie Wilson------------------ Scatman Crothers

#57. “Champs Ain’t Chumps”
Ed Brown---------------------- Jack Albertson
Chico Rodriguez-------------- Freddie Prinze
Louie Wilson------------------ Scatman Crothers
Salvador------------------------ Danny Mora

#58. “Ready When You Are, C.B.”
Ed Brown---------------------- Jack Albertson
Chico Rodriguez-------------- Freddie Prinze
Louie Wilson------------------ Scatman Crothers
Della Rogers------------------- Della Reese

#59. “Chico’s Padre”
Ed Brown---------------------- Jack Albertson
Chico Rodriguez-------------- Freddie Prinze
Louie Wilson------------------ Scatman Crothers

#60. “Black Tie Blues”
Ed Brown---------------------- Jack Albertson
Chico Rodriguez-------------- Freddie Prinze
Louie Wilson------------------ Scatman Crothers
Della Rogers------------------- Della Reese

#61. “Matchmaker, Matchmaker”
Ed Brown---------------------- Jack Albertson
Chico Rodriguez-------------- Freddie Prinze
Louie Wilson------------------ Scatman Crothers
Della Rogers------------------- Della Reese

#62. “Ed Talks to God”
Ed Brown---------------------- Jack Albertson
Chico Rodriguez-------------- Freddie Prinze
Louie Wilson------------------ Scatman Crothers
Della Rogers------------------- Della Reese

#63. “Louie’s Can Can”
Ed Brown---------------------- Jack Albertson
Louie Wilson------------------ Scatman Crothers
Della Rogers------------------- Della Reese
Salvador------------------------ Danny Mora

#64. “Gregory Peck is a Rooster”
Ed Brown---------------------- Jack Albertson
Louie Wilson------------------ Scatman Crothers
Della Rogers------------------- Della Reese
Salvador------------------------ Danny Mora

#65. “Uncle Sonny”
Ed Brown---------------------- Jack Albertson
Louie Wilson------------------ Scatman Crothers
Della Rogers------------------- Della Reese

Chico and the Man
Season Four: 1977-1978

#66. “Who’s Been Sleeping in My Car?”
Ed Brown---------------------- Jack Albertson
Raul Garcia-------------------- Gabriel Melgar
Louie Wilson------------------ Scatman Crothers
Della Rogers------------------ Della Reese

#67. “Su Casa, Mi Casa”
Ed Brown---------------------- Jack Albertson
Raul Garcia-------------------- Gabriel Melgar
Louie Wilson------------------ Scatman Crothers
Della Rogers------------------ Della Reese

#68. “Take Me, I’m Yours”
Ed Brown---------------------- Jack Albertson
Raul Garcia-------------------- Gabriel Melgar
Louie Wilson------------------ Scatman Crothers
Della Rogers------------------- Della Reese

#69. “The Third Letter”
Ed Brown---------------------- Jack Albertson
Raul Garcia-------------------- Gabriel Melgar
Louie Wilson------------------ Scatman Crothers
Della Rogers------------------ Della Reese

#70. “The Bed”
Ed Brown---------------------- Jack Albertson
Raul Garcia-------------------- Gabriel Melgar
Louie Wilson------------------ Scatman Crothers
Della Rogers------------------- Della Reese

#71. “Della and Son”
Ed Brown---------------------- Jack Albertson
Raul Garcia-------------------- Gabriel Melgar
Louie Wilson------------------ Scatman Crothers
Della Rogers------------------- Della Reese

#72. “The Matter of Privacy”
Ed Brown---------------------- Jack Albertson
Raul Garcia-------------------- Gabriel Melgar
Louie Wilson------------------ Scatman Crothers
Della Rogers------------------- Della Reese

#73. “Ed, the Hero”
Ed Brown---------------------- Jack Albertson
Raul Garcia-------------------- Gabriel Melgar
Louie Wilson------------------ Scatman Crothers
Della Rogers------------------ Della Reese

#74. “The Hot Rock”
Ed Brown---------------------- Jack Albertson
Raul Garcia-------------------- Gabriel Melgar
Louie Wilson------------------ Scatman Crothers
Della Rogers------------------- Della Reese

#75. “Ed’s Team”
Ed Brown---------------------- Jack Albertson
Raul Garcia-------------------- Gabriel Melgar
Louie Wilson------------------ Scatman Crothers
Della Rogers------------------- Della Reese

#76. “The Proposal”
Ed Brown---------------------- Jack Albertson
Raul Garcia-------------------- Gabriel Melgar
Louie Wilson------------------ Scatman Crothers
Della Rogers------------------ Della Reese

#77. “Aunt Charo”
Ed Brown---------------------- Jack Albertson
Raul Garcia-------------------- Gabriel Melgar
Louie Wilson------------------ Scatman Crothers
Della Rogers------------------ Della Reese
Aunt Charo-------------------- Charo

#78. “Charo Takes Over”
Ed Brown---------------------- Jack Albertson
Raul Garcia-------------------- Gabriel Melgar
Louie Wilson------------------ Scatman Crothers
Della Rogers------------------ Della Reese
Aunt Charo-------------------- Charo

#79. “The Americanization of Charo”
Ed Brown---------------------- Jack Albertson
Raul Garcia-------------------- Gabriel Melgar
Louie Wilson------------------ Scatman Crothers
Aunt Charo-------------------- Charo

#80. “Raul Runs Away (1)”
Ed Brown---------------------- Jack Albertson
Raul Garcia-------------------- Gabriel Melgar
Louie Wilson------------------ Scatman Crothers
Aunt Charo-------------------- Charo
Mando-------------------------- Isaac Ruiz

#81. “Raul Runs Away (2)”
Ed Brown--------------------- Jack Albertson
Raul Garcia------------------- Gabriel Melgar

#82. “Charo and the Matador”
Ed Brown--------------------- Jack Albertson
Raul Garcia-------------------- Gabriel Melgar
Louie Wilson------------------ Scatman Crothers
Aunt Charo-------------------- Charo

#83. “A New Girl in Town”
Ed Brown---------------------- Jack Albertson
Raul Garcia-------------------- Gabriel Melgar
Louie Wilson------------------ Scatman Crothers
Monica------------------------- Julie Hill

#84. “Waiting for Chongo”
Ed Brown---------------------- Jack Albertson
Raul Garcia-------------------- Gabriel Melgar
Louie Wilson------------------ Scatman Crothers
Monica------------------------- Julie Hill

#85. “Help Wanted”
Ed Brown---------------------- Jack Albertson
Raul Garcia-------------------- Gabriel Melgar
Louie Wilson------------------ Scatman Crothers
Monica------------------------- Julie Hill

#86. “Buenas, Dias, Mr. President”
Ed Brown---------------------- Jack Albertson
Raul Garcia-------------------- Gabriel Melgar
Louie Wilson------------------ Scatman Crothers
Monica------------------------- Julie Hill

#87. “Ed Brown’s Car Wash”
Ed Brown---------------------- Jack Albertson
Raul Garcia-------------------- Gabriel Melgar
Louie Wilson------------------ Scatman Crothers
Monica------------------------- Julie Hill

#88. “The Peeping Tom”
Ed Brown---------------------- Jack Albertson
Raul Garcia-------------------- Gabriel Melgar
Louie Wilson------------------ Scatman Crothers
Monica------------------------- Julie Hill

The only episode I'm not sure about is "Ed Brown Vs. The IRS". It has Della Reese's name in the opening credits, but I didn't see her in the episode. Maybe TV Land cut out her scene for that episode. Because for the other episodes, if she wasn't in them, her name was not in the opening credits.

Thank you so much for listing all the shows. I copied off the first 3 seasons as a reference when I'm watching Freddie in action. Your efforts are greatly appreciated.