Here's what will be airing on Start TV on Valentine's Day, all times Eastern:

6am: Strong Medicine-"Clinical Risk" (S6E3, OAD: June 26, 2005)
7am: Any Day Now-"It's a Mother-Daughter Thing" (S3E11, OAD: November 5, 2000)
8am: Touched by an Angel-"The Heart of the Matter" (S1E6, OAD: November 2, 1994)
9am: Murder, She Wrote-"Broadway Malady" (S1E13, OAD: January 13, 1985)
10am: Murder, She Wrote-"Murder to a Jazz Beat" (S1E14, OAD: February 3, 1985)
11am: Murder, She Wrote-"My Johnny Lies Over the Ocean" (S1E15, OAD: February 10, 1985)
12pm: Charmed-"Power Outage" (S3E7, OAD: November 16, 2000)
1pm: Charmed-"Primrose Empath" (S3E6, OAD: November 9, 2000)
2pm: Charmed-"Sleuthing with the Enemy" (S3E8, OAD: December 14, 2000)
3pm: Charmed-"Coyote Piper" (S3E9, OAD: January 11, 2001)
4pm: Charmed-"We All Scream for Ice Cream" (S3E10, OAD: January 18, 2001)
5pm: Gilmore Girls-"The Third Lorelai" (S1E18, OAD: March 22, 2001)
6pm: Gilmore Girls-"Emily in Wonderland" (S1E19, OAD: April 26, 2001)
7pm: Gilmore Girls-"P.S. I Lo..." (S1E20, OAD: May 3, 2001)
8pm: Gilmore Girls-"Love, Daisies and Troubadours" (S1E21, OAD: May 10, 2001)
9pm: Gilmore Girls-"Sadie, Sadie" (S2E1, OAD: October 9, 2001)
10pm: Charmed-"Blinded by the Whitelighter" (S3E11, OAD: January 25, 2001)
11pm: Charmed-"Wrestling with Demons" (S3E12, OAD: February 1, 2001)
12am: Charmed-"Bride and Gloom" (S3E13, OAD: February 8, 2001)
1am: Ghost Whisperer-"Speed Demon" (S2E14, OAD: February 2, 2007)
2am: Ghost Whisperer-"Mean Ghost" (S2E15, OAD: February 9, 2007)
3am: Ghost Whisperer-"The Cradle Will Rock" (S2E16, OAD: February 16, 2007)
4am: Medium-"Being Mrs. O'Leary's Cow" (S1E13, OAD: April 25, 2005)
5am: Medium-"In the Rough" (S1E14, OAD: May 2, 2005)