I was browsing The Fulton Critic and here are some of the shows that will start airing on cable and local affiliates in the upcoming years.

Malcolm in the Middle (starts syndication fall 2004, cable run on FX starts in 2008)

My Wife and Kids (syndication starts fall 2005, cable run starts on ABC Family in 2005)

The Bernie Mac Show (syndication starts fall 2005, cable run starts on FX in 2008)

Here's a few more that are sure fires......

According to Jim
The Gilmore Girls
Scrubs
George Lopez
Still Standing

Actually Gilmore Girls along w/ Smallville and Jamie Kennedy Epirement are enterint syndication on ABC Family THIS FALL.